Quantum Mechanics(QM) from Special Relativity(SR)
A physical derivation of Quantum Mechanics (QM) using only the
assumptions of Special Relativity (SR) as a starting point...
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The following is a derivation of Quantum Mechanics (QM) from Special
Relativity (SR). It basically
highlights the few extra physical assumptions necessary to generate QM given SR as the
base assumption.
A lot of the texts on Quantum Mechanics that I have seen start with a
few axioms, most of which are non-intuitive, and don't really seem to
be related to anything in classical physics. These assumptions
then
build up to the Schrödinger equation, at which point we have Quantum Mechanics. In the more advanced chapters, the books will then say
that we need a wave function that obeys Special Relativity, which the Schrödinger
equation does not.
They then proceed by positing the Klein-Gordon and Dirac equations, saying that
they are the relativistic versions of the Schrödinger equation. It is
then shown that these versions of QM agree very nicely with all of the
requirements of SR, and that in fact, things like the
spin-statistics theory come from the union of Quantum Mechanics and Special
Relativity.
But, one facet of quantum theory that has always intrigued me is this: Quantum
Mechanics seems to join up very well with Special Relativity,
but not with General Relativity (GR). Why?
Thinking along that line led me to the following ideas: Why do
the textbooks start with Schrödinger, and then say that Klein-Gordon
is the relativistic version? What if Quantum Mechanics can actually be
derived from Special Relativity? If so, then one can more correctly
state that the Schrödinger equation is actually the low-velocity (low-energy) limit
of the Klein-Gordon equation, just as Newtonian physics is the low-velocity limit of
Relativistic physics. Can you get Quantum Mechanics without the starting point
of the standard QM axioms? Can the axioms themselves actually be derived
from something that makes a little more sense, that is a little more connected
to other physics? So, starting
with SR, and it's two simple axioms (Invariance of the Measurement Interval,
Constancy of LightSpeed), what else do you actually need to
get QM?
Also, if it turned out that QM can be derived from SR, that would sort
of explain that difficulties of making it join up with GR. If
quantum theory is derivable from a "flat" Minkowski space-time, then GR
curvature effects are something above and beyond QM.
Since the language of SR is
beautifully expressed using 4-vectors, I will use that formalism. There
are quite a few different
variations of 4-vectors that can correctly describe SR. I use the one
that has only real
(non-complex) notation throughout SR. The imaginary unit ( i ) is
introduced only at the last step, which
gives QM. As you can note from the outline, there are only a few steps
necessary. By the way, SR is an excellent approximation for the
majority of the currently known universe, including on the
surface of Earth. It is only in the regions of extreme curvature,
such as near a stellar
surface or black hole, that GR is required.
See the 4-Vectors Reference for more
reasoning on
the choice of notation, and for more on four-vectors in general.
Interesting points include:
*All events, at which there may or may not be particles, massive or massless, have a 4-velocity magnitude of c,
the speed of light.
*A number of particle properties are simply constants times another
property.
*Wave-particle duality appears to occur purely within SR - ex.
Relativistic Optics, Relativistic Doppler Effect.
*Fields appear to occur purely within SR - Potential Momentum.
*QM is apparently generated simply by allowing the particles to move in
imaginary/complex spaces within
spacetime.
*The Quantum Superposition Principle, usually assumed as axiomatic, is
apparently a consequence of the Klein-Gordon equation being a linear
wave PDE.
Notation and Properties of SR 4-Vectors
guv = guv = DiagnolMatrix[1,-1,-1,-1] Minkowski
Spacetime Metric: This is the
"flat" spacetime of SR
A = Au = (at,ax,ay,az)
= (a0,a1,a2,a3) = (a0,a)
A typical 4-vector
Au = (at,-ax,-ay,-az)
= (a0,-a1,-a2,-a3) = (a0,-a)
A typical 4-covector; we can always get the 4-vector form with Au
= guvAv
A·B = guv Au Bv = Av
Bv = Au
Bu = +a0b0-a1b1-a2b2-a3b3
= +a0b0-a·b
The Scalar Product relation, used to make Lorentz Scalars
Useful Quantities
γ[v] = 1 / √[1-(v/c)2] : Lorentz Scaling Factor (gamma
factor)
τ[v,t] = t / γ : Proper Time
Sqrt[1+x] = √[1+x] ~ (1+x/2) for x<<1 : Math relation often used to
simplify Relativistic eqns. to
Newtonian eqns.
Fundamental/Universal Physical Constants (Lorentz Scalars)
c = Speed of Light
hbar = h/2π = ℏ = Planck's Reduced Const aka. Dirac's
Const
mo = Particle Rest Mass (varies with particle type)
Fundamental/Universal Physical 4-Vectors (Lorentz Vectors)
(this notation always places the c-factor in the time-like part, and
the name goes with the
space-like part)
4-Position R = (ct,r)
4-Velocity U = γ(c,u)
4-Momentum P = (E/c,p) = γ mo(c,u)
4-CurrentDensity J = (cρ,j) = γ
ρo(c,u)
4-WaveVector K = (ω/c,k) = 1/hbar (E/c,p)
4-Gradient ∂
= (∂/c∂t,-∂/∂x,-∂/∂y,-∂/∂z)
= (∂t/c,-∂x,-∂y,-∂z)
= (∂t/c,-del)
4-EM VectorPotential AEM = (ΦEM/c,
aEM)
4-EM PotentialMomentum QEM = qAEM
= q(ΦEM/c, aEM) = (UEM/c,
pEM) *includes effect of charge q*
4-TotalMomentum PT
= (H/c, pT) = P + QEM
4-TotalGradient D
= ∂ + iq/hbar AEM = 4-Gradient ∂
+ effects of Vector Potential
Fundamental/Universal Relations
R = R
U = dR/dτ "4-Velocity
is the derivative of 4-Position wrt. proper time"
P = moU
J = ρoU
K = 1/hbar P
∂ = -iK "This relation is usually written as a
correspondence
∂ ~ -iK , rather than a pure equality"
QEM = qAEM
PT = (H/c, pT)
= P + QEM
D = ∂ + iq/hbar AEM
"where AEM is the EM vector potential and q is the
EM charge"
Derived Physical Constants (Scalar Products of Lorentz Vectors give
Lorentz Scalars)
R·R = (Δs)2 = (ct)2-r·r
= (ct)2-|r|2
U·U = (c)2
P·P = (moc)2 : J·J
= (ρoc)2
K·K = (moc/hbar)2
∂·∂ = -(moc/hbar)2
"This relation
may require a bit more justification, but it works..."
Now then, how do we get QM out of SR?
Start with a special relativistic spacetime for which the invariant
measurement interval is given by R·R = (Δs)2 = (ct)2-r·r
= (ct)2-|r|2.
This is just a "flat" Euclidean 3-space with an extra, reversed-sign
dimension, time,
added to it.
This interval is Lorentz Invariant.
In this convention, space-like intervals are
(-)negative, time-like intervals are
(+)positive, and light-like intervals are (0)null.
One can say that the universe is the set of all possible events in
spacetime.
Events/Particles:
All of the Special Relativistic notation applies to the concept of events.
Events are simply points in spacetime. The measurement interval between
points is an invariant.
Now, let's examine the interesting events...
Let there exist particles (which can carry information) that move about
in this spacetime.
Each particle is located at an event (a time and a place) 4-Position R = (ct,r).
The factor of c is inserted in the time part to give the correct,
consistent dimension of length to
this 4-vector.
In fact, every SR 4-vector has this constant c-factor to give
consistent dimensions.
A particle is simply a self-sustaining event, or more correctly a
worldline of connected events,
which "carries" information forward in time.
The information that a particle can "carry" include mass, charge, any
of the various
hypercharges, spin, polarization, phase, frequency, energy, etc..
These are the particles' properties.
Motion/Dynamics:
Let these particles be able to move around within the spacetime.
The 4-Velocity of an event is given by U = dR/dτ,
or
the total derivative of the 4-Position with respect to its Proper Time.
This gives the 4-Velocity U = γ(c,u),
where γ(v) = 1
/ √[1-(v/c)2].
This particle, if its rest mass mo>0, moves only in the
direction of +time along its
own worldline Uworldline = (c,0).
Interestingly, all stationary (v = 0) massive particles move into the
future at c, the Speed of Light;
If the particle has rest mass mo = 0, it moves in a null or
light-like direction. This is
neither along time nor along space, but "between" them.
These light-like particles, with a v = c, have a 4-Velocity: Ulight-like
= Infinite
c(1,n), where n is a unit space vector.
Since this is rather undefined, we will use the 4-Wave Vector,
introduced later, to describe photons.
A particle only has a spatial velocity u with respect to
another particle or an observer.
We have the relation √(U·U) = c. This says that the
magnitude of the 4-velocity is
c, the speed of light. This result is general, massive or massless!
What all this means is that all light-like particles live on the
"surface" null-space of
the Light Cone, between time and space,
while all massive particles live within the "interior" the Light Cone.
Light Cone
| time-like interval(+)
/ light-like interval(0)
worldline
|
| c
\ future /
\ | /
\ |
/ -- space-like
interval(-)
\|/now
/|\
/
| \
elsewhere
/ | \
/ past \
| -c
Mass/Energy/Momentum:
One of the basic properties of particles is that of mass. Each particle
has a rest mass mo.
Rest mass is simply the mass as measured in a frame at rest with respect to an
observer.
This mass, along with the velocity of a particle, gives 4-Momentum P = moU.
Nature seems to indicate that one of the fundamental conservation laws
is the Conservation of
4-Momentum.
This comes from the idea that a system remains invariant under time or
space translations in an
isotropic, homogeneous universe.
The sum of all particle 4-Momenta involved in a given interaction is
constant; it has the same value
before and after a given interaction.
The 4-Momentum relation P = moU
gives 4-Momentum P = (E/c,p) = moU
= γmo(c,u).
This gives the Einstein Mass-Energy relation, E = γ moc2,
or E = mc2
where m = (γ mo).
Note that for light-like particles, the result using this formula is
undefined since Elight-like = Infinite
0 c2.
Presumably, the m = (γ mo) factor must scale in some
way (i.e. like a delta
function) to give reasonable results.
Also, there is a lot of confusion over whether m is the actual mass or not.
A simple thought experiment clears this up. Imagine an atom at rest,
having rest mass mo.
Now imagine an observer moving past the atom at near light speed.
The apparent mass of the atom to the moving observer is m = (γ mo).
Now imagine this observer accelerating to ever greater speeds.
The atom is sitting happy and unchanging in its own rest frame.
However, once the observer were going fast enough, this apparent mass m = (γ mo)
could be made to exceed that necessary to create a black hole.
As that would be an irreversible event, the gamma factor γ must simply be a
measure of the relative velocities of the two events.
So, the true measure of actual mass is just the rest mass mo.
Waves:
The energy of light-like particles can be obtained another way.
It turns out that every photon (light particle) has associated with it
a 4-WaveVector
K = (ω/c,k), where ω = temporal angular frequency.
Through the efforts of Planck, Einstein, and de Broglie, it was
discovered that K = ( 1 / hbar )P
= (ω/c,k) = 1/hbar (E/c,p).
Planck discovered h (hbar = h/2π) based on
statistical-mechanics/thermodynamic considerations of the blackbody problem.
Einstein applied Planck's idea to photons in the photoelectric effect to give E = hbar ω
and the idea of photons as particle quanta.
de Broglie realized that every particle, massive or massless, has 3-vector p
= hbar k.
Putting it all together naturally produces 4-vector P = hbar K
= (E/c,p) = hbar(ω/c,k).
Note also that the 4-WaveVector (a wave-like object) is just a
constant, hbar, times the
4-Momentum (a particle-like object).
This means that photons, or other massless quanta, can act like
localized particles and massive
quanta can act like non-localized waves.
That gives the Mass-Energy relation for all kinds of particles, ( E = γ
moc2 = hbar
ω ), and also gives the relation for m = (γ mo)
= ω hbar/c2
= (γωo)hbar/c2.
Note that massive particle would have rest frequency ωo , which
would look like (γ ωo) to an observer, while massless
particles simply have frequency ω.
This leads into the wave-particle duality aspect of nature, and we
haven't even gotten to QM yet!
Note: "There is a duality of particle and wave even in
classical mechanics, but the
particle is the senior partner, and the wave aspect has no opportunity
to display its unique
characteristics." - Goldstein, Classical Mechanics 2nd Ed., pg 489 (The
relation between
geometrical optics and wave mechanics using the Hamilton-Jacobi Theory).
I need to emphasize here that the 4-WaveVector can exist as an entirely
SR object (non-QM). It can
be derived in terms of periodic motion, where families of surfaces move
through space as time
increases, or alternately, as families of hypersurfaces in spacetime,
formed by all events passed by
the wave surface. The 4-WaveVector is everywhere in the direction of
propagation of the wave surfaces.
From this structure, one obtains relativistic/wave optics, without ever
mentioning QM.
I believe that there is more to the 4-WaveVector than other people
have figured on (i.e. more
importance to the overall phase of the waves). More on that later...
Also, the question always arises: What is waving? I assume that it is
simply an internal property of
a particle that happens to be cyclic. This would allow all particles to
be "waves", or
more precisely to have a cyclic period, without the need for a medium to be
waving in. Also, note that the
phase of the 4-WaveVector was not defined. Presumably, (2π) of
4-WaveVec's
could have the same 4-vector K .
However, another interpretation could be the symmetry between 4-vectors
and One-Forms, where the 4-vectors consist of "arrows" and one-forms
consist of "parallel lines". The length of arrow along the lines
is the dot-product operation, which results in a Lorentz scalar number.
Also, it is at this step that I believe a probabilistic description is
being imposed on the physics.
Spacetime Structure:
Now, let's get to the really tough stuff.
There is a thing called the 4-Gradient ∂
= (∂/c∂t,-∂/∂x,-∂/∂y,-∂/∂z)
= (∂t/c,-∂x,-∂y,-∂z)
= (∂t/c,-del),
where ∂ is the partial derivative function.
It tells you about the changes/variations in the "surface" of spacetime.
This 4-vector is significantly different from the others. It is a
function that acts on a value, not
a value itself.
It also has a negative sign in the space component, unlike the other
"physical type"
vectors.
When it is applied to the 4-CurrentDensity, it leads to the
Conservation of Charge equation.
∂·J = ∂/c∂t[cρ]+del·j
= ∂ρ/∂t +del·j = 0.
This says that the change in charge-density with respect to time is
balanced by the divergence or
spatial flow of current-density.
The same thing can be applied to particle 4-Momentum:
∂·P = ∂/c∂t[E/c]+del·p
= (1/c2)∂E/∂t
+del·p = 0.
∂E/∂t+c2del·p
= 0.
This says that the change in energy with respect to time is balanced by
the divergence or spatial
flow of momentum.
In fact, this is the 4-Vector Conservation of Momentum Law.
Energy is neither created nor destroyed, only transported from place to
place in the form of
momentum.
This is the strong, local form, of conservation - the continuity
equation.
Now comes Quantum Mechanics (QM)!
Now then, based on empirical evidence:
QM (and enhancements like QED and QFT) have given the correct
calculation/approximation of more phenomena
than any other theory, ever.
We have the following simple relation: ∂
= -i K or K
= i ∂.
Most books will call this a correspondence, rather than
a strict equality, whatever
that means.
This innocent-looking, very simple relation gives all of Standard QM,
by providing P = hbar
K = i hbar ∂.
In component form this is (E = i hbar ∂/∂t) and (p
= -i hbar del).
These are the standard operators used in the Schrödinger/Klein-Gordon
eqns (as well as other
relativistic quantum field equations), which are the basic QM
description of physical
phenomena.
This essentially gives the Unitary Evolution Axiom of QM, which governs
how the state of a quantum system evolves in time.
Let's summarize a bit:
We used the following relations:
(particle/location-->movement/velocity-->mass/momentum-->wave
duality-->spacetime
structure)
With the exception of 4-Velocity being the derivative of 4-Position, all of
these relations are just constants times other 4-Vectors.
| R = (ct,r) |
particle/location |
| U = dR/dτ |
movement/velocity |
| P = moU |
mass/momentum |
| K = 1/hbar P |
wave duality |
| ∂ = -iK |
spacetime structure |
By applying the Scalar Product law to these relations, we get:
U·U = (c)2
P·P = (moc)2
K·K = (moc/hbar)2
and, assuming that we can get away with it:
∂·∂ = (-imoc/hbar)2
= -(moc/hbar)2
Let's look at that last equation.
∂·∂ = (∂/c∂t,-del)·(∂/c∂t,-del)
= ∂2/c2∂t2-del·del
= -(moc/hbar)2,
| ∂2/c2∂t2
= del·del-(moc/hbar)2 |
This is the basic, free-particle, Klein-Gordon equation, the relativistic cousin of
the Schrödinger equation!
It is the relativistically-correct, quantum wave-equation for spinless (spin-0)
particles.
We have apparently discovered QM by multiplying with the
imaginary unit, ( i ).
Essentially, it seems that allowing SR relativistic particles to move
in an imaginary/complex space
is what gives QM.
At this point, you have the simplest relativistic quantum wave equation.
The principle of quantum superposition follows from this, as this wave
equation (a linear PDE) obeys the superposition principle.
The quantum superposition axiom tells what are the allowable (possible)
states of a given quantum system.
I believe that the only other necessary postulate to really get all of
standard QM is the
probability interpretation of the wave function, and that likely is simply
reinterpretation of the continuity equation, ∂·J
= ∂/c∂t(cp)
+ del·j = ∂p/∂t + del·j =
0,
where J is taken to be a "particle" current density.
The Klein-Gordon equation is more general than the Schrödinger
equation, but simplifies to the Schrödinger
equation in the (v/c)<<1 limit.
Also, extensions into EM fields (or other types of relativistic
potentials) can be made using D = ∂ + iq/hbar
AEM
where AEM is the EM vector potential and q is the EM
charge,
and allowing D·D = -(moc/hbar)2
to be the more
correct EM quantum wave equation.
Potentials/Fields:
Let's back up to the 4-Momentum equation. Momentum is not just a
property of individual particles, but also of fields.
These fields can be described by 4-vectors as well.
One such relativistically invariant field is the 4-EM VectorPotential AEM,
which is itself a function of 4-Position X.
4-EM VectorPotential AEM [X] = AEM
[(ct,x)] = (ΦEM/c, aEM) = (ΦEM[(ct,x)]/c, aEM[(ct,x)]),
where the [(ct,x)] means is a function of time t and position x.
While a particle exists as a worldline over spacetime, the
4-VectorPotential exists over all spacetime.
The 4-VectorPotential can carry energy and momentum, and interact with
particles via their charge q.
PotentialMomentum:
One may obtain the PotentialMomentum 4-vector by multiplying by a
charge q, QEM = qAEM
4-EM PotentialMomentum QEM = qAEM
= q(ΦEM/c,
aEM) = (UEM/c, pEM)
The 4-TotalMomentum is then given by PT =
P + QEM
This includes the momentum of particle and
field, and it is the locally conserved quantity.
4-TotalMomentum PT
= (H/c,pT),
where these are the TotalEnergy=Hamiltonian and 3-TotalMomentum.
P = PT - QEM
= moU
Now working back, we can make our dynamic 4-Momentum more generally, including
the effects of potentials.
4-Momentum P = (E/c,p) = (H/c
- UEM/c,pT - pEM)
= (H/c - qΦEM/c,pT - qaEM)
The dynamic 4-momentum of a particle thus now has a component
due to the 4-VectorPotential,
and reverts back to the usual definition of 4-momentum in the case of
zero 4-VectorPotential.
Likewise, following the same path as before...
K = 1/hbar P
4-WaveVector
K = (ωT/c - (q/hbar)ΦEM/c, kT
-
(q/hbar)aEM)
∂ = -iK
4-Gradient ∂
= (∂T/c∂t - (iq/hbar)ΦEM/c,-delT
- (iq/hbar)aEM) = (∂t /c,-del)
Define 4-TotalGradient D = ∂ + iq/hbar AEM
In addition, we can go back to the velocity formula:
u = c2
(p)/(E) = c2 (pT - qa)/(H - qΦ)
Lagrangian/Hamiltonian Formalisms:
The whole Lagrangian/Hamiltonian connection is given by the relativistic
identity:
( γ - 1/γ ) = ( γβ2 )
Now multiply by your favorite Lorentz Scalars... In this case for
a free relativistic particle
( γ - 1/γ )(P·U) = ( γβ2 )(P·U)
( γ - 1/γ )(moc2) = ( γβ2 )(moc2)
( γmoc2 - moc2/γ ) = γmoc2β2
( γmoc2 - moc2/γ ) = γmov2
( γmoc2 ) + (- moc2/γ ) = γmou·u
( γmoc2 ) + (- moc2/γ ) =
( p·u
)
( H ) + ( L ) = ( p·u )
The Hamiltonian/Lagrangian connection falls right out
Now, including the effects of the 4- Vector Potential A=(Φ/c,
a) { = (ΦEM/c,
aEM) for EM potential }
Momentum due to Potential Q = qA
Total Momentum of system PT
= Π
= P
+ Q = P + qA = moU
+ qA = (H/c,pT) = (γmoc+q Φ/c,γmou+q a)
A·U = γ(Φ - a·u
) = Φo
P·U = γ(E - p·u
) = Eo
PT·U = Eo+ qΦo = moc2
+ qΦo
I assume the following:
A = (Φo/c2) U
= (Φ/c,
a) = Φo/c2 γ(c, u) = ( γΦo/c, γΦo/c2u)
giving (Φ = γΦo and
a = γΦo/c2u)
This is analogous to P = Eo/c2 U
( γ - 1/γ )(PT·U) = ( γβ2 )(PT·U)
γ(PT·U) + -(PT·U)/γ = ( γβ2 )(PT·U)
γ(PT·U) + -(PT·U)/γ =
(pT·u)
( H ) + ( L ) = (pT·u)
|
L = -(PT·U)/γ = -moc2/γ - qΦ + qa·u |
H = γ(PT·U)
= γmoc2 + qΦ = γmoc2 + qγΦo =
γ(moc2 + qΦo) |
H + L = pT·u
|
L = -(PT·U)/γ
L = -((P + Q)·U)/γ
L = -(P·U + Q·U)/γ
L = -P·U/γ - Q·U/γ
L = -moU·U/γ - qA·U/γ
L = -moc2/γ - qA·U/γ
L = -moc2/γ - q(Φ/c,
a)·γ(c, u)/γ
L = -moc2/γ - q(Φ/c,
a)·(c, u)
L = -moc2/γ - q(Φ - a·u)
L = -moc2/γ - qΦ + qa·u
L = -moc2/γ - qΦo/γ
L = -(moc2
+ qΦo)/γ
|
H = γ(PT·U)
H = γ((P + Q)·U)
H = γ(P·U + Q·U)
H = γP·U + γQ·U
H = γmoU·U + γqA·U
H = γmoc2 + qγΦo
H = γmoc2 + qΦ assuming A
= (Φo/c2) U
H = ( γβ2 + 1/γ )moc2 + qΦ
H = ( γmoβ2c2 + moc2/γ ) + qΦ
H = ( γmov2 + moc2/γ ) + qΦ
H = p·u + moc2/γ + qΦ
H = E + qΦ
H = ± c√[mo2c2+p2] + qΦ
H = ± c√[mo2c2+(pT-qa)2] + qΦ
|
H + L =
γ(PT·U) - (PT·U)/γ
(γ - 1/γ)(PT·U)
( γβ2 )(PT·U)
( γβ2 )(moc2 + qΦo)
(γmoβ2c2 + qγΦoβ2)
(γmou·uc2/c2
+ qΦoγu·u/c2)
(γmou·u + qa·u)
assuming A = (Φo/c2) U
(p·u + qa·u)
pT·u
|
Lets's now show that the Schrödinger equation is just the low energy limit of
the Klein-Gordon equation.
We now let the Klein-Gordon equation use the TotalGradient, so now our wave
equation uses EM potentials.
D·D = -(moc/hbar)2(∂
+ iq/hbar AEM)·(∂ + iq/hbar
AEM) + (moc/hbar)2 =
0
let A'EM = iq/hbar AEM
let M = moc/hbar
then (∂ + A'EM)·(∂ + A'EM)
+ (M)2 = 0
∂·∂ + ∂·A'EM + 2 A'EM·∂
+ A'EM·A'EM + (M)2
= 0
now the trick is that factor of 2, it comes about by keeping track of
tensor notation...
a weakness of strick 4-vector notation
let the 4-Vector potential be a conservative field, then ∂·AEM
= 0
(∂·∂) + 2(A'EM·∂) + (A'EM·A'EM)
+ (M)2 = 0
expanding to temporal/spatial components...
( ∂t2/c2-del·del ) +
2(φ'/c ∂t/c - a'·del
) + ( φ'2/c2- a'·a' ) + (M)2 = 0
gathering like components
( ∂t2/c2 + 2φ'/c ∂t/c
+ φ'2/c2
) - (del·del + 2
a'·del + a'·a' ) + (M)2 = 0
( ∂t2 + 2φ'∂t
+ φ'2 ) - c2(del·del +
2 a'·del +
a'·a'
) + c2(M)2 = 0
( ∂t + φ' )2 - c2(del + a' )2 + c2(M)2
= 0
multiply everything by (i hbar)2
(i hbar)2( ∂t + φ' )2 - c2(i
hbar)2(del + a'
)2 + c2(i hbar)2(M)2
= 0
put into suggestive form
(i hbar)2( ∂t + φ' )2 = - c2(i
hbar)2(M)2 + c2(i hbar)2(del
+ a' )2
(i hbar)2( ∂t + φ' )2
= i2c2(i hbar)2(M)2
+ c2(i hbar)2(del + a' )2
(i hbar)2( ∂t + φ' )2
= i2c2(i hbar)2(M)2
[1 + c2(i hbar)2(del + a' )2/ i2c2(i
hbar)2(M)2 ]
(i hbar)2( ∂t + φ' )2
= i2c2(i hbar)2(M)2
[1 + (del + a' )2/
i2(M)2 ]
take Sqrt of both sides
(i hbar)( ∂t + φ' ) = ic(i hbar)(M)
Sqrt[1 + (del + a' )2/
i2(M)2 ]
use Newtonian approx Sqrt[1+x] ~ ±[1+x/2] for x<<1
(i hbar)( ∂t + φ' ) ~ ic(i hbar)(M)
±[1 + (del + a' )2/2
i2(M)2 ]
(i hbar)( ∂t + φ' ) ~ ±[ic(i hbar)(M)
+ ic(i hbar)(M)(del + a'
)2/2 i2(M)2 ]
(i hbar)( ∂t + φ' ) ~ ±[c(i2 hbar)(M)
+ c( hbar)(del + a'
)2/2(M) ]
remember M = moc/hbar
(i hbar)( ∂t + φ' ) ~ ±[c(i2 hbar)(moc/hbar)
+ c( hbar)(del + a'
)2/2(moc/hbar) ]
(i hbar)( ∂t + φ' ) ~ ±[c(i2)(moc)
+ (hbar)2(del + a'
)2/2(mo) ]
(i hbar)( ∂t + φ' ) ~ ±[-(moc2)
+ (hbar)2(del + a'
)2/(2mo) ]
remember A'EM = iq/hbar AEM
(i hbar)( ∂t + iq/hbarφ ) ~
±[-(moc2)
+ (hbar)2(del + iq/hbara )2/2mo ]
(i hbar)( ∂t ) + (i hbar)(iq/hbar)(φ)
~ ±[-(moc2) + (hbar)2(del
+ iq/hbara )2/2mo
]
(i hbar)( ∂t ) + (i2)(qφ ) ~
±[-(moc2) + (hbar)2(del
+ iq/hbara )2/2mo
]
(i hbar)( ∂t ) -(qφ ) ~ ±[-(moc2)
+ (hbar)2(del + iq/hbara )2/2mo ]
(i hbar)( ∂t ) ~ (qφ )±[-(moc2)
+ (hbar)2(del + iq/hbara )2/2mo ]
take the negative root
(i hbar)( ∂t ) ~ (qφ ) + [(moc2)
- (hbar)2(del + iq/hbara )2/2mo ]
(i hbar)( ∂t ) ~ (qφ ) + (moc2)
- (hbar)2(del + iq/hbara )2/2mo
call (qφ ) + (moc2) = V[x]
(i hbar)( ∂t ) ~ V[x] - (hbar)2(del
+ iq/hbara )2/2mo
typically the vector potential is zero in most non-relativistic settings
(i hbar)( ∂t ) ~ V[x] - (hbar)2(del)2/2mo
And there you have it, the Schrödinger Equation with a potential
The assumptions for non-relativistic equation were:
Conservative field AEM, then ∂·AEM
= 0
(del + a' )2/ i2(M)2
= (del + a' )2/ i2(moc/hbar)2
= (hbar)2(del + a'
)2/ i2(moc)2 is near zero
i.e. (hbar)2(del + a'
)2 << (moc)2, a good
approximation for low-energy systems
Arbitrarily chose vector potential a=0
Or keep it around for a near-Pauli equation (we would just have to
track spins, not included in this derivation)
Note that the free particle solution ∂·∂ = -(moc/hbar)2
is
shown to be a limiting case for AEM = 0.
Again, see the 4-Vectors Reference for
more on this.
Now, let's examine something interesting...
∂·∂ = -(moc
/ hbar)2: Klein-Gordon Relativistic Wave eqn.
∂ = -i/hbar P
∂·(-i/hbar P) =
-(moc
/ hbar)2
∂·(P) = - i (moc)2
/ hbar
∂·(P) = 0 - i (moc)2
/ hbar
but, ∂·(P) = Re[∂·(P)],
by definition, since the 4-Divergence of any 4-Vector (even a
Complex-valued
one) must be Real
so ∂·(P) = 0 : The
conservation of 4-Momentum (i.e. energy&momentum) for our
Klein-Gordon
relativistic particle.
This is also the equation of continuity which leads to
the probability interpretation in the Newtonian limit.
So, the following assumptions within SR-Special Relativity lead to
QM-Quantum Mechanics:
| R = (ct,r) |
Location of an event (i.e. a particle)
within spacetime |
| U = dR/dT |
Velocity of the event is the derivative
of position with respect to Proper
Time |
| P = moU |
Momentum is just the Rest Mass of the
particle times its velocity |
| K = 1/hbar P |
A particle's wave vector is just the
momentum divided by Planck's constant, but
uncertain by a phase factor |
| ∂
= -iK |
The change in spacetime corresponds to
(-i) times the wave vector, whatever
that means... |
| D = ∂
+ iq/hbar AEM |
The particle with minimal coupling
interaction in a potential field
|
Each relation may seem simple, but there is a lot of complexity
generated by each level.
It can be shown that the Klein-Gordon equation describes a non-local
wave function, which "violates
relativistic causality when used to describe particles localized to
within more than a Compton
wavelength,..."-Baym. The non-locality problem in QM is also the
root of the EPR paradox. I
suspect that all of these locality problems are generated by the last
equation, where the factor of
( i ) is loaded into the works, although it could be at the
wave-particle duality equation. Or
perhaps we are just not interpreting the equations correctly since we
derived everything from SR,
which should obey its own relativistic causality.
Let's examine the last relation on a quantum wave ket vector |V>:
∂ = -iK
∂ |V> = -iK |V> which gives time eqn.[∂/c∂t |V>
=
-iω/c
|V>] and space eqn.[-del |V> = -ik |V>]
A solution to this equation is:
|V> = vn e^(-i Kn·R) |Vn>
where vn
is a real number, |Vn> is an eigenstate (stationary state)
Generally, |V> can be a superposition of eigenstates |Vn>
N
|V> = Sum [vn e^(-i Kn·R) |Vn>]
n = 1
Going back to the 4-wave vector K, I believe that this is
the part of the derivation of QM
from SR that the quantum probabilistic interpretation becomes
necessary. Since the 4-wave vector as
given here does not define the phase relationship, there is some
ambiguity or uncertainty in the
description. Phase almost certainly plays some role. Again, presumably
2*Pi of 4-wave vectors could
describe the same 4-momentum vector. Once one starts taking waves to be
the primary description of a
system, the particle aspect gets lost, or smeared out. Once the
gradient operation is added to the
mix, one gets what is essentially a diffusion equation for waves, in
which the particle aspect is
lost. Thus, a probabilistic interpretation is needed, showing that the
particle is located
somewhere/when in the spacetime, but can't quite be pinned down
exactly. My bet is that if the
phases could be found, the exact locations of particle events would
arise.
This remains a work in progress.
Reference papers/books can be found in the 4-Vectors
Reference.
Email me, especially if you notice errors or have
interesting comments.
Please, send comments to John
